REACTION OFo-BENZOQUINONE MONO-IMINE WITHo-AMINOPHENOL
نویسندگان
چکیده
منابع مشابه
Transformation of acetaminophen by chlorination produces the toxicants 1,4-benzoquinone and N-acetyl-p-benzoquinone imine.
The reaction of the common pain reliever acetaminophen (paracetamol, 4-acetamidophenol) with hypochlorite was investigated over time under conditions that simulate wastewater disinfection. Initially, the reaction was studied in pure water at neutral pH (7.0), a range of reaction times (2-90 min), and a molar excess of hypochlorite (2-57 times) relative to the acetaminophen concentration. The re...
متن کاملStructural Properties of 4-Substituted Phenols Capable of Proton-Coupled Electron Transfer to Superoxide
The structural properties of 4-substituted phenols capable of proton-coupled electron transfer (PCET) to superoxide (O2 ) were investigated on the basis of electrochemical and electron spin resonance (ESR) spectral measurements and supported by density functional theory calculations. Although the proton and electron donating abilities of phenols are considered to be important factors in PCET re...
متن کاملwithO - the - Shelf RISC
Multithreaded architectures have been proposed for future multiprocessor systems due to their ability to cope with network and synchronization latencies. Some of these architectures depart signiicantly from current RISC processor designs, while others retain most of the RISC core unchanged. However, in light of the very low cost and excellent performance of oo-the-shelf microprocessors it seems...
متن کاملN-acetyl-p-benzoquinone imine induces Ca2+ release from mitochondria by stimulating pyridine nucleotide hydrolysis.
The mechanism of N-acetyl-p-benzoquinone imine (NAPQI)-induced release of Ca2+ from rat liver mitochondria was investigated. The addition of NAPQI or 3,5-Me2-NAPQI (a dimethylated analogue of NAPQI with only oxidizing properties) to mitochondria resulted in the rapid and extensive oxidation of NADH and NADPH. High-performance liquid chromatographic analysis of mitochondrial pyridine nucleotides...
متن کاملBenzoquinone-promoted reaction of O2 with a Pd(II)-hydride.
Benzoquinone (BQ) and O(2) are among the most common stoichiometric oxidants in Pd-catalyzed oxidation reactions. The present study provides rare insights into mechanistic differences between BQ and O(2) in their reactivity with a well-defined Pd-hydride complex, Pd(IMes)(2)(H)(O(2)CPh) (1). BQ promotes the reductive elimination of PhCO(2)H from 1 and catalyzes the formation of a Pd(II)-OOH com...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Chemistry Letters
سال: 1974
ISSN: 0366-7022,1348-0715
DOI: 10.1246/cl.1974.293